POSSIBLE INDIRECT MEASUREMENT OF DIFFUSION COEFFICIENT FROM MIGRATION KINETIC ESSAY OF FOOD PACKAGING

José E. Manzoli, Celso Lemos, Luz C.G.A. Panzarini, Juliana S. Félix, Magali Monteiro

Abstract

Diffusion coefficient is an important quantity that affects any migration process on food or nutritional systems. Special care has to be done to migration of undesirable substances from packaging into foods, if the diffusion is the only process involved in mass transfer. The Fick´s equation resolution permits to describe the kinetic of migration from polymer packaging into food or simulant, once it was given the correct contour and initial conditions. Another important quantity is the partition coefficient, which quantifies the relation between the final or equilibrium concentrations in polymer and that in the food or simulant. Here it is proposed a simple procedure, based on numerical resolution of the Fick´s equation, where the diffusion coefficient could indirectly be measured, if the kinetic of migration had been measured and the partition coefficient is known.

Keywords

diffusion, migration, packaging

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IMEKO-TC24-2008-011.pdf

DOI

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IMEKO TC

TC24 - Chemical Measurements

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