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INTEGRATE APPROACH TO THE CALIBRATION OF NITROGEN OXIDES ANALYSERS AND TO THE EVALUATION OF THEIR MEASUREMENT UNCERTAINTY

Elena Amico di Meane, Davide Baroncini, Stefano Crispu, Gian Carlo Piras, Michela Sega

Abstract

The present work describes the approach to evaluate in a metrological correct and exhaustive way the contribution of the several sources to the uncertainty related to the calibration of nitrogen oxides (NO<sub>X</sub>) analysers, focusing in particular on non dispersive infrared (NDIR) analysers. In order to minimize the contribution due to the uncertainty on the composition of the calibration standards, gas mixtures of NO<sub>X</sub> prepared with the gravimetric method are used. The performances of two different techniques, namely NDIR and chemiluminescence, are compared by analysing primary reference gas mixtures prepared at the Istituto Nazionale di Ricerca Metrologica (INRIM), having concentrations within 100 mmol·mol<sup>-1</sup> of NO<sub>X</sub>.

Keywords
nitrogen oxides, NDIR spectroscopy, chemiluminescence
Download
IMEKO-WC-2009-TC24-161.pdf
DOI
-
IMEKO TC
TC24 - Chemical Measurements

Event details

Event
XIX IMEKO World Congress
Place
Lisbon, PORTUGAL
Time
6 September 2009 - 11 September 2009
Website
http://www.imeko2009.it.pt/

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