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FABRICATION AND CHARACTERIZATION OF FERROELECTRIC POLY (VINYLIDENE FLUORIDE -CO -TRIFLUOROETHYLENE) NANODOTS

Yoon-Young Choi, Moonkyu Park, Jongin Hong, Kwangsoo No

Abstract

We demonstrated a facile route to fabricate ferroelectric poly(vinylidene fluoride-trifluoroethylene), P(VDF-TrFE), nanodots from spin-coated thin films. Importantly, the discrete P(VDF-TrFE) nanodots possessed high degree of &beta;-phase [<i>F</i>(&beta;) > 60%] when compared to the fraction of &beta;-phase in thin films [<i>F</i>(&beta;) = 51%]. P(VDF–TrFE) nanodots of (51.4 &plusmn; 10.6) nm in height and (172.75 &plusmn; 40.5) nm in diameter displayed superior piezoresponse values (18.1 &plusmn; 3.3) pm/V and a low coercive voltage (2.4 &plusmn; 0.5) V. This offers our rationale for a great promise in non-volatile memories, infrared sensor arrays and artificial skin applications.

Keywords
ferroelectric P(VDF-TrFE) nanodots, spin coating, dewetting, piezoresponse force microscopy
Download
IMEKO-WC-2012-SS2-P5.pdf
DOI
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Event details

Event
XX IMEKO World Congress
Place
Busan, REPUBLIC of KOREA
Time
9 September 2012 - 12 September 2012
Website
http://imeko2012.kriss.re.kr

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