Transition metal complexes, possessing redox-isomerism as a basis for new smart sensing materials

Alla V. Arapova, Michail P. Bubnov, Nina A. Skorodumova, Natalia N. Smirnova, Gleb A. Abakumov

Abstract

Extensive studies on bistable molecules which can transform their physical properties with external stimuli, for developing molecule-based sensors have been performed [1-3]. It is known that some semiquinonato transition metal complexes undergo a redox-isomeric (valence-tautomeric) interconversion induced by temperature, light, pressure and magnetic field. This paper presents results of thermodynamic studies of some complexes which exhibit redoxisomerism.

Keywords

redox-isomerism, o-semiquinonic complexes of cobalt, thermodynamic properties

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IMEKO-TC4-2014-421.pdf

DOI

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IMEKO TC

TC4 - Measurement of Electrical Quantities

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